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"FLUORESCENCE-this type of glow is usually violet in color and most noticeable around the inside surface of the glass bulb. It is most pronounced on power tubes and is the product of electron bombardment of the glass taking place within the tube. It generally has no adverse affect upon receiver performance, and in fact, tubes displaying this phenomenon are particularily good with respect to gas content."
"Many materials flouresce or "glow" when struck by electrons. Not all the electrons in a vacuum tube strike the plate. A few stray off and strike other things in the tube, such as the glass envelope. Many types of glass will give off a faint blue glow when bombarded by electrons of sufficient energy. This is the most common type of blue glow seen in power output tubes. Often you will see small patches of glow that correspond to the holes in the plate or other structures in the tube."